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A person gives their Power of Attorney to someone they trust to act for them in all the ways the POA spells out. They must be of sound mind when they do so.
The fact that you are putting your wife in a memory care facility next week suggests she is not of sound mind.
But having said that, an attorney would question your wife out of your presence to make sure she understood what she was signing. If he is satisfied she understands that she is asking you to make decisions for her, then it might not be too late.
If for your wife, only your wife can decide who she wishes to be her Power of Attorney and she would need to be able to understand the legal document. Is she still able to do that being that since she has Alzheimer's/Dementia?