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As Pam suggests, D.C. has a lot of resources. I also searched on "D.C, Veteran's housing", and "Section 8 Housing, D.C."
If he's a Veteran, you might want to try that source first; I'm sure there's a lot of red tape involved, but according to VA newsletters, it's making more intense efforts to address homelessness of Vets.
Good luck; it's kind of you to be concerned about this person.